Product description and parameters
Full name and product positioning
Product full name: Wacker VINNOL® H 40/60 vinyl chloride-vinyl acetate copolymer resin (commonly known as VC/VAc resin)
VINNOL® H 40/60 is a vinyl chloride-vinyl acetate binary copolymer produced by Wacker (Germany) using suspension polymerization, with a vinyl acetate content of approx. 39 wt%. It belongs to the higher-viscosity, more flexible grades of the VINNOL H40 series. It can be used as a binder or copolymer binder for solvent-based coatings, printing inks and adhesives, and can also be dissolved in various acrylic monomers for modifying solvent-free systems.
Core technical parameters
Parameter
Typical value / range
Appearance
White powder
Vinyl chloride (VC) content
Approx. 61 wt%
Vinyl acetate (VAc) content
Approx. 39 wt%
Chlorine content
34.0 – 35.2 wt%
K value
59 – 61
Solution viscosity (20% MEK solution, 20 °C)
150 – 210 mPa·s
Flow time (20% MEK solution)
Approx. 145 s
Volatile content
< 2.0 wt%
Glass transition temperature Tg
Approx. 62 °C
Weight-average molecular weight Mw
100,000 – 140,000 g/mol
Density
1.31 g/cm³
Bulk density
Approx. 750 kg/m³
Particle size
< 1.0 mm
Solubility
Ketones are good solvents; esters dissolve it alone; soluble in styrene, MMA, acrylate and other monomers; insoluble in alcohols and aliphatic hydrocarbons
Food-contact compliance
Complies with FDA 21 CFR §175.105 and §175.300 (used in the corresponding applications)
Packaging
25 kg/bag
Core advantages
· High vinyl acetate content gives good film flexibility and can help lower the heat-seal temperature and softening point
· Can be dissolved alone in ester solvents and is also soluble in monomers such as styrene, methyl methacrylate and acrylates, making it convenient as an additive in solvent-free pure-monomer systems
· Compatible with ester-soluble nitrocellulose in a 50/50 ratio range, which helps modify NC systems
· Fully compatible with other VINNOL® series resins; viscosity, flexibility and heat-seal performance can be adjusted by blending
· Films offer good abrasion resistance, water resistance, oil resistance and resistance to dilute acids and alkalis, salt water and brine
Main application areas
· Core applications: solvent-based printing inks, paper and film coatings, strippable protective lacquers, heat-sealable coatings, wood varnishes, architectural mortar paints, road-marking paints
· Suitable areas: copolymer binder for flexible ink formulations, solubilization in weak-solvent (ester / glycol ester / glycol ether) systems, adhesion and pigment-wetting modification for solvent-free pure-monomer UV / monomer systems
· Not recommended: direct blending with alkyd resins, polyvinyl acetal or polyvinyl butyral (generally incompatible); avoid pigments containing zinc, cadmium and iron oxides (they may catalyze decomposition of VC copolymers at high temperature); avoid direct contact with iron containers to prevent discoloration; long-term outdoor use requires separate blending with weathering stabilizers